Heat and Thermodynamics · Thermal expansion and anomalous expansion of water
Q1. Water has maximum density at:
- (a) 0°C
- (b) 4°C
- (c) 25°C
- (d) 100°C
Answer & solution
Answer: (b) 4°C
Correct Answer: 4°C — Option (b)
Water exhibits a unique property called anomalous expansion: unlike most liquids, water expands (becomes less dense) when cooled below 4°C and also when heated above 4°C. At 4°C, water reaches its maximum density of approximately 1000 kg/m³ (1 g/cm³). Above 4°C, water expands normally as temperature increases (density decreases). Below 4°C, as temperature drops toward 0°C, water molecules begin to form hydrogen bonds that push them apart into the open hexagonal crystal lattice structure of ice — causing water to expand and become less dense. This is why ice floats on water (ice is less dense than liquid water at 4°C). This anomalous expansion has significant ecological importance as it ensures water bodies freeze from the top down, preserving aquatic life.
Option (a) 0°C — Incorrect: At 0°C, water either freezes into ice or is just at the freezing point; it has lower density than at 4°C because the hydrogen-bonded lattice structure begins forming below 4°C.
Option (c) 25°C — Incorrect: At room temperature (25°C), water is well above 4°C and has a density of approximately 997 kg/m³, which is less than the maximum density at 4°C.
Option (d) 100°C — Incorrect: At 100°C, water is at its boiling point and has a density of about 958 kg/m³, which is significantly lower than the maximum density at 4°C.
Water exhibits a unique property called anomalous expansion: unlike most liquids, water expands (becomes less dense) when cooled below 4°C and also when heated above 4°C. At 4°C, water reaches its maximum density of approximately 1000 kg/m³ (1 g/cm³). Above 4°C, water expands normally as temperature increases (density decreases). Below 4°C, as temperature drops toward 0°C, water molecules begin to form hydrogen bonds that push them apart into the open hexagonal crystal lattice structure of ice — causing water to expand and become less dense. This is why ice floats on water (ice is less dense than liquid water at 4°C). This anomalous expansion has significant ecological importance as it ensures water bodies freeze from the top down, preserving aquatic life.
Option (a) 0°C — Incorrect: At 0°C, water either freezes into ice or is just at the freezing point; it has lower density than at 4°C because the hydrogen-bonded lattice structure begins forming below 4°C.
Option (c) 25°C — Incorrect: At room temperature (25°C), water is well above 4°C and has a density of approximately 997 kg/m³, which is less than the maximum density at 4°C.
Option (d) 100°C — Incorrect: At 100°C, water is at its boiling point and has a density of about 958 kg/m³, which is significantly lower than the maximum density at 4°C.